Model studies on flavin-dependent carbonyl-activation: reduction of carbonyl compounds by flavohydroquinone.

نویسندگان

  • G Blankenhorn
  • S Ghisla
  • P Hemmerich
چکیده

The reduction of aldehydes by flavohydroquinone to yield the corresponding alcohols and flavoquinone is reported and discussed in view of its relevance to the mechanism of flavin-dependent dehydrogenation and carbonyl activation. With formaldehyde and flavohydroquinone formation of a covalent 5(HO — CH2)Fl red~ intermediate species is observed. In a reverse reaction 5-methylflavoquinonium cation undergoes an internal redox reaction to yield flavohydroquinone and formaldehyde.

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عنوان ژورنال:
  • Zeitschrift fur Naturforschung. Teil B. Anorganische Chemie, organische Chemie, Biochemie, Biophysik, Biologie

دوره 27 9  شماره 

صفحات  -

تاریخ انتشار 1972